CONTENTS of journal "INDUSTRIAL PRODUCTION AND USE OF ELASTOMERS" 1·2020 (Russia)
DOI: https://doi.org/10.24411/2071-8268-2020-10101
RUSSIAN SYNTHETIC RUBBER INDUSTRY IN 2019 (p. 3-10)
Aksyonov V.I.,
OBRAKADEMNAUKA (Garibaldi ul., 4g, Moscow, Russia, 119313)
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ABSTRACT
In this report presents a comparative analysis of the results of the work of Russian enterprises
for the production of synthetic rubbers in 2019, the main changes in global capacity, supply and demand, the main events that occurred and are planned in 2020 and the next 2-3 years are considered.
KEYWORDS: synthetic rubber, power, consumption, production, export, domestic, market, change.
For citation: Aksyonov Viktor I. Proizvodstvo sinteticheskikh kauchukov rossiyskimi kompaniyami v 2019 godu [Russian synthetic rubber industry in 2019]. Prom. Proizvod. Ispol'z. Elastomerov, 2020, no. 1,pp. 3-10. (In Russ.). DOI: 10.24411/2071-8268-2020-10101 (In Russ.).
DOI: https://doi.org/10.24411/2071-8268-2020-10102
THE EFFECT OF ELECTRONIC DISCHARGE ON PHENOL DERIVATIVES (p. 11-13)
Manukyan Anna S., Rybkin Vladimir V.,
Ivanovo State University of Chemical Technology, 153000, Ivanovo, Russia
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ABSTRACT
The decomposition products of phenol derivatives under the electron discharge action are described, and their decomposition processes are analyzed. The characteristics of the processes showed general regularities in the plasma impact on phenol and its derivatives. It is shown the decomposition kinetics has a pseudo-first order for the substance concentration. The order of magnitude of the velocity constants is the same; plasma-forming gases have the same regularities. The solution pH tends to the alkaline part under the discharge action. It is also described the addition of the •OH radical trap and the Fenton reagent have the same effect on the decomposition of phenol and its derivatives..
KEYWORDS: electronic discharge, phenol, phenol derivatives.
For citation: Manukyan Anna S., Rybkin Vladimir V. The effect of electronic discharge on phenol derivatives. Prom. Proizvod. Ispol'z. Elastomerov, 2020, no. 1, pp. 11-13. (In Russ.). DOI: 10.24411/2071- 8268-2020-10202.
DOI: https://doi.org/10.24411/2071-8268-2020-10103
APPLICATION IN THE PRODUCTION OF EMULSION RUBBERS OF THE COMBINED COAGULANT SODIUM CHLORIDE – CATION ELECTROLYTE (p. 14-19)
Nasyrov I.Sh., Faizova V.Yu., Kapanova R.A., Nikulina N.S., Nikulin S.S., Verezhnikov V.N.,
Nasyrov I.Sh., TAU NefteKhim (14, Tekhnicheskaya ul., Sterlitamak, 453110, Russia)
Faizova V.Yu., Sterlitamak Petrochemical Plant, NefteKhim (14, Tekhnicheskaya ul., Sterlitamak, 453110, Russia)
Kapanova R.A., Sterlitamak Petrochemical Plant, NefteKhim (14, Tekhnicheskaya ul., Sterlitamak, 453110, Russia)
Nikulina N.S., Voronezh Institute of the State Fire Service of the Ministry of Emergency Situations of Russia (231, Krasnoznamenaya st., Voronezh, 394052, Russia)
Nikulin S.S., Voronezh State University of Engineering Technologies (19, Revolutcii prosp., Voronezh, 394000, Russia)
Verezhnikov V.N., Voronezh State University (1 Universitetskaya pl., Voronezh, 394018, Russia)
ABSTRACT
The coagulating ability of two cationic electrolytes — cetylpyridinium bromide and cetyltrimethylammonium bromide and a combined coagulant based on sodium chloride and the above two cationic electrolytes on the process of rubber isolation from latex was assessed. It has been established that the completeness of coagulation is affected by the consumption of coagulating and acidifying agents. The use of a combined coagulant makes it possible to achieve the complete release of rubber from latex at asodium chloride consumption of about 120 kg / t of rubber and a cationic electrolyte consumption of 10 kg/t of rubber. By their main indicators, the resulting rubbers and vulcanizates correspond to the requirements.
KEYWORDS: latex, sodium chloride, cationic electrolyte, isolation, rubber, vulcanizates, indicators.
For citation: Nasyrov I.Sh., Faizova V.Yu., Kapanova R.A., Nikulin N.S., Nikulin S.S., Verezhnikov V.N. The use in the production of emulsion rubbers of the combined coagulant sodium chloride/cationic electrolyte. Prom. Proizvod. Ispol'z. Elastomerov, 2020, no. 1, pp. 14-19. DOI: 10.24411/2071-8268-2020- 10103.
DOI: https://doi.org/10.24411/2071-8268-2020-10104
RHEOLOGY OF PHENOL AND HIGHLY POLAR POLYOLS CONDENSATION PRODUCTS (p. 20-24)
Ovchinnikov Kirill A., Sklyuev Prokofiy V., Malinovskaya Jylia A., Pimenov Andrei A.,
Samara State Technical University,443100, Samara, Russia
ABSTRACT
The article provides information on the dynamic viscosity of polymers obtained by condensation according of phenol-formaldehyde resins and variosly highly polar polyols. In addition, the article presents data on increasing the viscosity of resins during reaction with an acid initiator for various ratios of reagents.
KEYWORDS: phenol, polyols, resins, dynamic viscosity.
For citation: Ovchinnikov K.A., Sklyuev P.V., Malinovskaya YU.A., PimenovA.A. Rheology of phenol and highly polar polyols condensation products. Prom. Proizvod. Ispol'z. Elastomerov. 2020, no. 1, pp. 20- 24. (In Russ.). DOI: 10.24411/2071-8268-2020-10104.
DOI: https://doi.org/10.24411/2071-8268-2020-10105
DEVELOPMENT OF CHEMISTRY AND TECHNOLOGY OF BIOPOLYMER LIGNIN (p. 25-39)
Karimov O.Kh., Teptereva G.A., Chetvertneva I.A., Movsumzade E.M.,
Karimov O.Kh., MIREA — Russian Technological University (78 Vernadsky Avenue, Moscow 119454, Russia).
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Teptereva G.A., Ufa State Petroleum Technological University, (1, Kosmonavtov ul, 450062, Ufa, Russia)
Chetvertneva I.A., Volga-Ural region of LLC SBM Service Center (12, Universitetskiy prospekt, Moscow, 119330, Russia).
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Movsumzade E.M., Ufa State Petroleum Technological University, 450062, Ufa, Russia; Russian state university im. A.N. Kosygina (Technologies. Design. Art) (33, bldg. 1, Sadovnicheskaya ul., Moscow, 115035, Russia)
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ABSTRACT
The article presents the history of the formation and development of the chemistry of biopolymer lignin from the moment of its discovery to the present.In the context of the development of ideas about the structure of the lignin molecule and its properties, the methods and technologies of using biopolymer are shown. The analysis of possible areas for further research and promising technologies for the use of lignin is given.
KEYWORDS: lignin, biopolymer, cellulose, bioplastic.
For citation: Karimov O.Kh., Teptereva G.A., Chetvertneva I.A., Movsumzade E.M. Development of chemistry and technology of biopolymer lignin. Prom. Proizvod. Ispol'z. Elastomerov. 2020, no. 1, pp. 25-39. (In Russ.). DOI: 10.24411/2071-8268-2020-10105.
DOI: https://doi.org/10.24411/2071-8268-2020-10106
INFLUENCE OF E-181 EPOXY RESIN ON NBR BASED RUBBERS (p. 40-44)
Vostrikov Dmitriy S., Bochkarev Yevgeniy S,. Lopatina Svetlana S., Dimitrov Pavel V., Vaniyev Marat A.,
Volgograd State Technical University (28, Lenin avenue, Volgograd, 400005, Russia)
ABSTRACT
There was investigated the influence of E-181 epoxy resin on properties of NBR (28% acrylonitrile content) based rubbers. It was found out that if epoxy resin content is 10 phr. then the best tensile strength (1,2-1,8 times more) and better elongation at break can be provided after open air aging at 120°C. The achieved positive effect on improving the dynamic properties and wear resistance is due to the reactions of grafting of the resin to the rubber macromolecule, which can take place both at the stage of rolling and at the stage of vulcanization. For the maximum modifying effect, it is proposed to introduce epoxy resin directly into the rubber, followed by processing on rollers for 3-5 minutes. Different times of rubber rolling in the presence of epoxy resin and different order of E-181 introduction are due to the fact that it was necessary to assess the influence of these parameters on the modification features in terms of the efficiency of grafting reactions, as well as on the final properties of rubber. After exposure in diesel fuel at 100°C the modified rubbers show lower properties deterioration. E-181 epoxy resin influence on lowtemperature properties was also investigated..
KEYWORDS: nitrile-butadiene rubber, epoxy resin, heat resistance, low-temperature resistance, diesel fuel, modification..
For citation: Vostrikov Dmitriy S., Bochkarev Yevgeniy S,.Lopatina Svetlana S,. Dimitrov Pavel V., Vaniyev Marat A. Vliyaniye epoksidnoy smoly E-181 na svoystva rezin na osnove butadiyen-nitril'nogo kauchuka [Influence of E-181 epoxy resin on NBR based rubbers]. Prom. Proizvod. Ispol'z. Elastomerov, 2020, no. 1, pp. 40-44. (In Russ.).
DOI: https://doi.org/10.24411/2071-8268-2020-10107
RESEARCH INFLUENCE OF BORON NITRIDE ON THE HEAT RESISTANCE OF RUBBER COMPOUND BASED ON HYDROGENATED ACRYLONITRILE-BUTADIENE RUBBER (p. 45-48)
Ushmarin Nikolay F., Spiridonov Ivan S., Mukhametgaleev Azat G., Kol'tsov Nikolay I.,
Ushmarin Nikolay F., Cand.Sci. (Tech). Cheboksary Production Association named V.I. Chapaev (1, Socialistic ul., Cheboksary, 420006, Russian Federation)
Spiridonov Ivan S., Leading Process Engineer. Cheboksary Production Association named V.I. Chapaev (1, Socialistic ul., Cheboksary, 420006, Russian Federation)
Mukhametgaleev Azat G., Deputy Director. Sintegra LLC (Russia, 423582, Nizhnekamsk, OPS-12)
Kol'tsov Nikolay I., Dr Sci. (Chem.), Prof. Chuvash State University (15, Moscow prosp., Cheboksary, 420015, Russian Federation
ABSTRACT
The effect of boron nitride on the rheometric and physicomechanical properties of the rubber mixture and vulcanizates based on the hydrogenated nitrile butadiene rubber Terban 3406 is investigated. It is established that hexagonal boron nitride has practically no effect on the kinetics and duration of vulcanization of the rubber mixture. An increase of content boron nitride in the rubber mixture leads to an increase in stress at a given elongation and tear resistance at room temperature of the vulcanizates, a slight increase of their elastic strength at 150°C and temperature of the onset of destruction.
KEYWORDS: hexagonal nitride bor, rheometric, physical and mechanical properties, hydrogenated butadiene-nitrile caoutchouc Terban 3406, rubber mixture, vulcanizates.
For citation: Ushmarin N.F., Spiridonov I.S., Mukhametgaleev А.G., Kol'tsov N.I. Research influence of boron nitride on the heat resistance of rubber compound based on hydrogenated acrylonitrile-butadiene rubber. Prom. Proizvod. Ispol'z. Elastomerov, 2020, no. 1, pp. 45-48. DOI: 10.24411/2071-8268-2020- 10107.
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